French ingenue Melanie Laurent was most excited to meet “Gossip Girl” star Matthew Settle at the premiere of her film “The Adopted.” The “Inglourious Basterds” star “beelined to him,” said a spy at a Soho Grand after-party. “She confessed her obsession for the show, telling Matthew she learned English from it.” Also at the Cinema Society/Dior Beauty screening were Woody Harrelson, Isla Fisher, Mark Ruffalo, Jesse Eisenberg and Dylan McDermott. [Page Six]